Single crystals with the Sillenite structure, Bi12MO20 (M=Si, Ge, Ti) have a fortunate combination of electro-optic, acousto-optic and piezoelectric properties and are thus promising materials for optoelectronics. The fabrication of sillenite oxide thin-film structures by different techniques permits the development of a long list of devices, including integrated-optics devices. The strong spectral dependence of the photoconductive properties of these crystals and their electro-optic properties makes it possible to develop a wide variety of devices including spatial light modulators, hologram recording devices, phase conjugation, photorefractive incoherent-to-coherent optical converters. The relatively large electro-optic effect of sillenite oxide makes them useful also for optical fiber electric field sensors with high thermostability. |
Material |
BSO |
BGO |
BTO |
Chemical Formula |
Bi12SiO20 |
Bi12GeO20 |
Bi12TiO20 |
Crystal Structure |
Crystal
System: cubic |
||
Lattice Parameters, Å |
10.104 |
10.145 |
10.175 |
Density, g/cm3 |
9.14 |
9.2 |
9.2 |
Mohs Hardness |
6 |
5 |
5 |
Melting Point, °C |
884 |
925 |
840 |
Transparency Range, m |
0.4 - 6 |
0.4 - 7 |
0.5 - 6 |